Chemical News
Environmental feasibility of sustainable co-production of xylooligosaccharides and bioplastic from poplar sawdust
DOI: 10.1039/D5GC01539A, Paper


We evaluate the life-cycle environmental performance of producing xylooligosaccharides and bioplastic from poplar sawdust, demonstrating the environmental infeasibility of acetic acid pretreatment for xylooligosaccharides production.
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Enhancing Verbena officinalis L. antioxidant yield through natural deep eutectic solvents and MOF synergetic application
DOI: 10.1039/D5GC01721A, PaperHaixiang Li, Kunze Du, Chong Liu, Yumin Yang, Cailin Ye, Xiaoxia Li, Yanxu Chang
A green extraction strategy was developed for bioactives from Verbena officinalis using NADES and MOFs, enabling efficient enrichment, antioxidant activity enhancement, and component analysis supported by DFT and machine learning.
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Synthesis of value-added N-containing aromatic products from lignins: a review
DOI: 10.1039/D5GC00061K, Critical ReviewZimin Zhong, Yaqiu Zhao, Xiaolin Luo, Mengjun Xiao, Sibao Liu, Li Shuai, Lu Chen
This review focuses on various activation strategies for cleaving the lignin C–C/C–O bonds while forming new C–C/C–N bonds in the presence of transition metal and metal-free catalysts.
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Lignin refinery based on efficient thermo-photo-catalysis of Ru-RuO2/TiO2-Deep Eutectic Solvents
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC02098K, PaperHekun Ding, Yue Pan, Ao Zhan, Jie Lv, Yang Yang, Zhiyuan Yang, James H. Clark, Qiang Yu
A Lignin refinery with high-yields and high-selectivities towards aromatic monomers under mild conditions is challenging. A thermo-photo-catalysis system based on deep eutectic solvents (DESs) and Ru-RuO2/TiO2 is described here and...
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DOI: 10.1039/D5GC02098K, PaperHekun Ding, Yue Pan, Ao Zhan, Jie Lv, Yang Yang, Zhiyuan Yang, James H. Clark, Qiang Yu
A Lignin refinery with high-yields and high-selectivities towards aromatic monomers under mild conditions is challenging. A thermo-photo-catalysis system based on deep eutectic solvents (DESs) and Ru-RuO2/TiO2 is described here and...
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Plasmon-Driven Enhancement in CO2 Photoreduction: Mechanistic Elucidation and Materials Design Strategies
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC03066H, Tutorial ReviewHouxu Zhou, Suwei Wang, Pin Song, Yi Zhang, Wei Jiang, Jun Di
Under the background of global carbon neutrality, photocatalytic reduction of carbon dioxide (CO2) technology has become a research hotspot due to its sustainability and energy conversion potential. However, traditional photocatalysts...
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DOI: 10.1039/D5GC03066H, Tutorial ReviewHouxu Zhou, Suwei Wang, Pin Song, Yi Zhang, Wei Jiang, Jun Di
Under the background of global carbon neutrality, photocatalytic reduction of carbon dioxide (CO2) technology has become a research hotspot due to its sustainability and energy conversion potential. However, traditional photocatalysts...
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Heterostructure of Hollow MoSe2@CoSe for Stable Sodium Storage
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC03294F, PaperKai Yang, Wenrui Zhang, Qinghua Deng, Zhiqian Li, Jiancheng Zhang, Quanli Liu, Hao Mo, Nan Zhu
Transition metal selenides (TMSs) with excellent redox reversibility and high capacity have been considered as potential anodes for sodium-ion batteries (SIBs). However, low intrinsic conductivity and volume expansion of TMSs...
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DOI: 10.1039/D5GC03294F, PaperKai Yang, Wenrui Zhang, Qinghua Deng, Zhiqian Li, Jiancheng Zhang, Quanli Liu, Hao Mo, Nan Zhu
Transition metal selenides (TMSs) with excellent redox reversibility and high capacity have been considered as potential anodes for sodium-ion batteries (SIBs). However, low intrinsic conductivity and volume expansion of TMSs...
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Kinetic-controlled difunctionalization of olefins to α-hydroxycarbonyls under catalyst-free conditions†
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC02308D, Communication
Open Access
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Hong-Yu Hou, Yuan-Yuan Cheng, Xin-Yu Zhang, Ke Zhang, Hui-Zhen Ren, Kaiyi Su, Zhiyuan Huang, Bin Chen, Chen-Ho Tung, Li-Zhu Wu
Difunctionalization of olefins is effective to construct diverse valuable molecules. However, such reaction always relies on catalysts to control activity and selectivity. Herein, a catalyst-free difunctionalization of olefins with sulfonyl,...
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DOI: 10.1039/D5GC02308D, Communication


Difunctionalization of olefins is effective to construct diverse valuable molecules. However, such reaction always relies on catalysts to control activity and selectivity. Herein, a catalyst-free difunctionalization of olefins with sulfonyl,...
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Electroenzymatic cascade synthesis of 2,3-diaminophenazine on HRP-ZnGa2O4 nano-biohybrids
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC03726C, PaperYuxuan Cheng, Zhe Wang, Si-Qi Li, Meixuan Li, Xue Xiao, Yucheng Jiang, Yu Chen
In this work, a novel nano-biohybrid is developed for the efficient synthesis of 2,3-diaminophenazine (DAP), a biologically significant heterocyclic compound, via an electroenzymatic cascade catalysis. The horseradish peroxidase (HRP) is...
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DOI: 10.1039/D5GC03726C, PaperYuxuan Cheng, Zhe Wang, Si-Qi Li, Meixuan Li, Xue Xiao, Yucheng Jiang, Yu Chen
In this work, a novel nano-biohybrid is developed for the efficient synthesis of 2,3-diaminophenazine (DAP), a biologically significant heterocyclic compound, via an electroenzymatic cascade catalysis. The horseradish peroxidase (HRP) is...
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Advancing lignocellulosic conversion though biosensor-enabled metabolic engineering
DOI: 10.1039/D5GC03618F, Tutorial Review


Biosensor-aided metabolic engineering is advancing the conversion of lignocellulosic biomass by enabling regulation and optimization of microbial production pathways.
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Improved rare earth elements recycling using a sustainable diglycolamide-based hydrophobic eutectic solvent
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01707F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Baptiste Bernicot, Guilhem Arrachart, Sandrine Dourdain, Nicolas Schaeffer, Ana Dias, Stéphane Pellet-Rostaing
The sustainable recycling of rare earth elements (REEs) is crucial for the environment due to their role in enabling green technologies. Hydrometallurgical techniques, such as liquid-liquid extraction, are commonly used...
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DOI: 10.1039/D5GC01707F, Paper


The sustainable recycling of rare earth elements (REEs) is crucial for the environment due to their role in enabling green technologies. Hydrometallurgical techniques, such as liquid-liquid extraction, are commonly used...
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Fe3S4/Ni3S2 heterostructure realizing highly-efficient electrocatalysis of ethylene glycol and alkaline electrolyte to produce high value-added chemicals and hydrogen
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC02244D, PaperHongwei Ren, Jun-Ming Zhang, Tianjun Hu, Yongfeng Li, Haocheng Zhao, Ergui Luo, He Xiao, Man Zhao, Jingxiao Tang, Jianfeng Jia
Electrocatalytic water splitting is considered as a green and promising strategy for hydrogen production. Replacing the sluggish oxygen evolution reaction (OER) with thermodynamically favorable ethylene glycol oxidation reaction (EGOR) enables...
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DOI: 10.1039/D5GC02244D, PaperHongwei Ren, Jun-Ming Zhang, Tianjun Hu, Yongfeng Li, Haocheng Zhao, Ergui Luo, He Xiao, Man Zhao, Jingxiao Tang, Jianfeng Jia
Electrocatalytic water splitting is considered as a green and promising strategy for hydrogen production. Replacing the sluggish oxygen evolution reaction (OER) with thermodynamically favorable ethylene glycol oxidation reaction (EGOR) enables...
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Utilisation of reactive ionic liquids for energy storage and regulation of the power grid
DOI: 10.1039/D5GC02519B, Perspective


Chlorine is an essential feedstock for polymers and pharmaceuticals, with annual production exceeding 100 Mt.
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Powering lignocellulose biorefineries with solar energy – a critical review with furfural as a case study
DOI: 10.1039/D5GC01462J, Critical Review


In the context of the defossilization of the chemical industry, integrating solar-powered chemical transformation into biorefinery plants unlocks novel strategies and synergies for future plant designs.
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Biobased amide surfactants derived from cellulose-waste hydroxy acids: mechanochemical synthesis, foam fractionation and performance
DOI: 10.1039/D5GC01806D, Paper


A series of hydroxycarboxylic acids (HAs) with excellent hydrophilic properties are produced from alkali treatment of cellulose-containing materials. These HAs are then used in the production of biobased amide surfactants using mechanochemistry.
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Low-temperature plasma-enabled CO2 dissociation: a critical analysis of plasma setups and conversion mechanisms toward scale-up valorization
DOI: 10.1039/D5GC02037A, Critical ReviewYuxuan Xu, Yuan Gao, Liguang Dou, Dengke Xi, Chong Qi, Baowang Lu, Tao Shao
This review analyzes recent advances and limitations in low-temperature plasma-enabled CO2 dissociation setups and mechanisms, proposing a strategic outlook for the techno-economic feasibility toward scale-up valorization.
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Using a bioderived CO2-responsive polymer as an easily removed pressure sensitive adhesive
DOI: 10.1039/D5GC00630A, Paper


Combining renewable resources with CO2-responsive functionalities produced a pressure sensitive adhesive with adhesive properties like commercial cellophane tapes but can be easily removed from substrates using carbonated water at the end of life.
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An atomically dispersed Pt/γ-Mo2N(O0.3) catalyst for hydrogen production via aqueous-phase reforming of methanol
DOI: 10.1039/D5GC02092A, PaperYeteng Gong, Hengyue Xu, Yongsheng Li, Yaxuan Jing, Xiaohui Liu, Yanqin Wang, Yong Guo
Aqueous-phase reforming (APR) of methanol has emerged as a promising approach for hydrogen production.
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Hydrogenation-induced selective degradation of PET wastes
DOI: 10.1039/D5GC02071A, PaperBeibei Tan, Ming Lv, Xiaotian Qi, Zhiliang Huang
A novel hydrogenation-induced hydrothermal degradation strategy was demonstrated for upcycling of a range of real-life PET wastes into high-value 1,4-cyclohexanedicarboxylic acid (1,4-CHDA) and ethylene glycol (EG) in excellent yields under simple neutral water conditions.
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Electrolytic olefin epoxidation for sustainable synthesis of epoxy compounds
DOI: 10.1039/D5GC02487K, Tutorial ReviewHong-Ru Li, Chao-Yang Jing, Shan-Shan Chen, Alexander O. Terent'ev, Liang-Nian He
Electrolytic olefin epoxidation is a sustainable alternative to the thermocatalytic epoxidation. This article provides a state of the art overview in this field, focusing on the formation strategy of the reactive oxygen species.
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CO2-responsive membrane separation systems: a green solution for efficient separations
DOI: 10.1039/D5GC00220F, Critical ReviewLing Lei, Haohao Liu, Yunxiang Bai, Chunfang Zhang, Mingjie Yin, Wentao Wang, Liangliang Dong
CO2-responsive membrane separation systems represent an exciting separation technology owing to their ability to achieve controlled and efficient separation processes.
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