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Production of high-carbon-number hydrocarbon bio-aviation fuels via catalytic hydrogenation of vanillin and non-catalytic condensation: a mechanistic study with DFT and experimental insights
DOI: 10.1039/D5GC00281H, Paper
Open Access 
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jina Eun, Jeonghun Kim, Han Byeol Kim, Do Heui Kim, Jae-Wook Choi, Kwang Ho Kim, Chun-Jae Yoo, Seongmin Jin, Kyeongsu Kim, Hyunjoo Lee, Chang Soo Kim, Kwan-Young Lee, Jong Suk Yoo, Seo-Jung Han, Keunhong Jeong, Jeong-Myeong HaLignocellulose or lignin present significant potential as sustainable feedstocks to replace petroleum-derived resources through catalytic upgrading.
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Sustainable chemo-enzymatic NADP(H) synthesis from biomass-derived xylose, polyphosphate, and nicotinamide
DOI: 10.1039/D5GC00983A, PaperKai-Cheng Wang, Shota Nishikawa, Wan-Wen Ting, Xue-Hong Luo, Takumi Takahashi, Tony Z. Jia, Min-Hsuan Huang, Kosuke Fujishima, I-Son Ng, Po-Hsiang Wang
Chemo-enzymatic NAD(P)H synthetic strategy from biomass-derived crude xylose and nicotinamide.
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Enhancing selectivity and stability in electrochemical CO2 reduction using tailored sputtered CuAg electrodes
DOI: 10.1039/D4GC06164K, PaperMathias van der Veer, Nick Daems, Pegie Cool, Tom Breugelmans
A bimetallic CuAg alloy with 1% Ag, offers a promising method to convert captured CO2 to valuable chemicals, such as ethylene and ethanol.
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Integrated design of multifunctional reinforced bioplastics (MReB) to synergistically enhance strength, degradability, and functionality
DOI: 10.1039/D4GC02440K, Paper
Open Access 
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jinghao Li, Wei Liu, Alex Chang, Zachariah Foudeh, Jiali Yu, Peiran Wei, Kainan Chen, Cheng Hu, Dhatt Puneet, Susie Y. Dai, Joshua S. YuanBioplastics have emerged as a tangible solution to the plastic waste crisis.
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Synergistic nanoalloy PdCu/TiO2 catalyst for in situ hydrogenation of biomass-derived furfural at room temperature
DOI: 10.1039/D5GC00006H, PaperChand Adarsh Ashwani, Palanivel Subha, Lavanya Yalagandula, Christophe Len, Satyapaul A. Singh, Putla Sudarsanam
The PdCu nanoalloy supported on TiO2 nanorods effectively catalyzed the in situ hydrogenation of furfural at room temperature, showcasing efficient catalyst reusability and reaction scalability without requiring high-pressure conditions.
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Upgrading biomass-derived glycerol into terminal olefins via molybdenum-catalyzed carbon-chain extension
DOI: 10.1039/D5GC00843C, PaperHan Yin, Xiangtao Kong, Rui Lu, Xi Zhang, Wenbing Yu, Huifang Jiang, Xuhai Zhu, Fang Lu
A novel molybdenum-catalyzed process for carbon-chain extension of glycerol has been developed to produce 1,5-hexadiene.
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Sustainable potassium sorbate production from triacetic acid lactone in food-grade solvents
DOI: 10.1039/D4GC04832F, PaperMin Soo Kim, Sarang S. Bhagwat, Leoncio Santiago-Martínez, Xiaolei Shi, Kyuhyeok Choi, Jeremy S. Guest, George W. Huber
We propose a sustainable route to produce triacetic acetic acid (TAL)-derived potassium sorbate (KS) in food-grade solvents such as IPA and EtOH.
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Activating dynamic Zn–ZnO interface with controllable oxygen vacancy in CO2 electroreduction for boosting CO production
DOI: 10.1039/D5GC00955C, PaperXueqi Liu, Jingmin Ge, Shiying Li, Huanhuan Yang, Huiwen Tian, Hongpo Liu, Yaxi Li, Xiaoli Zheng, Yapeng Tian, Xinwei Cui, Qun Xu
ZnO undergoes in situ reconstruction into Zn@ZnO with controllable Zn–ZnO interfaces and oxygen vacancies, which boosted CO2RR-to-CO.
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Ambient and green processing of lead-free double perovskite Cs2AgBiBr6 films
DOI: 10.1039/D5GC00722D, Paper
Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Qian Chen, Abhinav K. Singh, Hissah Alghathami, Xuzhao Liu, Kun Huang, Andrew G. Thomas, Richard J. Curry, Laurie J. Phillips, Amanda J. HughesA green and simple method for processing high-quality lead-free perovskite Cs2AgBiBr6 films under ambient conditions for future optoelectronic applications.
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Natural deep eutectic solvents (NaDES): green solvents for pharmaceutical applications and beyond
DOI: 10.1039/D4GC06386D, Critical Review
Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Emma Chevé-Kools, Young Hae Choi, Catherine Roullier, Gwenaël Ruprich-Robert, Raphaël Grougnet, Florence Chapeland-Leclerc, Frank HollmannThis review first provides a comprehensive overview of NaDES theory and subsequently explores all potential applications of NaDES in the pharmaceutical industry, highlighting overlooked issues such as toxicity and process limitations.
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Synergistic SiO2@NC core–shell nanospheres enhance catalytic hydrogenation of lignin-derived aromatic aldehydes
DOI: 10.1039/D5GC00857C, PaperQian Jiang, Shuguang Xu, Zuzhi Li, Xingjie Guo, Rui Zhang, Zhicheng Jiang, Bi Shi
The design of heterogeneous catalysts to enhance substrate adsorption and hydrogen spillover plays a key role in the hydrogenation of biomass-derived chemicals.
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Lignin valorization through microbial production of polyhydroxyalkanoates: recent trends, challenges and opportunities
DOI: 10.1039/D5GC00370A, Critical ReviewZhe Liang, Sivasamy Sethupathy, Dang Wenqian, Hu Jinhao, Daochen Zhu
This review explores recent advances in lignin depolymerisation and its conversion into polyhydroxyalkanoates (PHA) via microbial biotransformation. It evaluates the opportunities and challenges in enhancing sustainable PHA production from lignin.
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Order–disorder hybrid high-entropy Co–Cu-Fe–Mn–Ce oxides for photothermal CO2 hydrogenation
DOI: 10.1039/D5GC01073J, PaperXin-Yan Wei, Zhen-Hong He, Mei-Xia Yang, Hui Ma, Wen-Jing Shi, Kuan Wang, Hongye Zhao, Weitao Wang, Huan Wang, Zhao-Tie Liu
CoCuMnFeCeOx high-entropy oxides exhibit exceptional performance in the photothermal catalytic reduction of CO2 to CO.
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Correction: Chitosan-based inks for 3D printing and bioprinting
Green Chem., 2025, 27,5388-5388
DOI: 10.1039/D5GC90073E, Correction Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Mohsen Taghizadeh, Ali Taghizadeh, Mohsen Khodadadi Yazdi, Payam Zarrintaj, Florian J. Stadler, Joshua D. Ramsey, Sajjad Habibzadeh, Somayeh Hosseini Rad, Ghasem Naderi, Mohammad Reza Saeb, Masoud Mozafari, Ulrich S. Schubert
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DOI: 10.1039/D5GC90073E, Correction
Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Mohsen Taghizadeh, Ali Taghizadeh, Mohsen Khodadadi Yazdi, Payam Zarrintaj, Florian J. Stadler, Joshua D. Ramsey, Sajjad Habibzadeh, Somayeh Hosseini Rad, Ghasem Naderi, Mohammad Reza Saeb, Masoud Mozafari, Ulrich S. SchubertThe content of this RSS Feed (c) The Royal Society of Chemistry
Engineering Yarrowia lipolytica as a green yeast cell factory for de novo biosynthesis of daidzein and puerarin
DOI: 10.1039/D5GC00180C, PaperTao Qian, Wenping Wei, Jiayun Xu, Ping Zhang, Mengfan Li, Yihui Zhu, Xiaochuan Chen, Bang-Ce Ye
Isoflavones are natural polyphenolic secondary metabolites found in legumes and play crucial roles in human health.
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Biomass-derived sustainable hypergolic rocket propellants with hydrogen peroxide
DOI: 10.1039/D5GC00255A, Paper
Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Ramlithin Mavila Chathoth, Charlie Oommen, Michael Gozin, Srinivas Dharavath, Manojkumar Jujam, Deepan Chowdhury, Jagadish DasTo mitigate the harmful environmental impact of chlorinated combustion products arising from traditional rocket propellants and replace highly hazardous hydrazine-based propellants, biomass-derived sustainable rocket propellants are developed.
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Design of a cage–core–chain structure catalyst for deep catalytic oxidative desulfurization with enhanced substrate enrichment
DOI: 10.1039/D5GC00838G, PaperRan Liu, Chang Wang, Xiangxiang Gao, Chen Liu, Jianmin Lv, Yusheng Zhang, Xinying Liu, Ndzondelelo Bingwa, Yali Yao, Fa-tang Li
Developing composite metal–organic framework (MOF) catalysts that integrate target molecule enrichment and reactive oxygen species generation to enhance oil–water biphasic desulfurization efficiency remains challenging.
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Enhanced electrocatalytic CO2 reduction to methane via synergistic Sb and F dual-doping on copper foil under pulsed potential electrolysis
DOI: 10.1039/D5GC00648A, PaperKuan Wan, Xue Jiang, Xin-Peng Li, Zhe Cao, Zhen-Hong He, Weitao Wang, Huan Wang, Xiaojuan Lai, Zhao-Tie Liu
A copper foil-based catalyst with abundant interfaces was constructed through electrodeposition to achieve Sb and F dual doping on the copper surface, enabling efficient CH4 production through pulsed CO2 electrolysis.
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One-pot oximation-Beckmann rearrangement under mild, aqueous micellar conditions
DOI: 10.1039/D5GC00958H, PaperMaryam Nabi, Kirti Sharma, Raj S. Wandre, Amol B. Gade
A sustainable and eco-friendly approach to the one−pot oximation−Beckmann rearrangement has been developed, leveraging nanomicelles to facilitate the reaction in water under mild conditions.
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Efficient continuous flow oxidation of furfural to maleic anhydride using O2 as a green oxidant
DOI: 10.1039/D4GC06305H, Paper
Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jonas Mortier, Christian V. Stevens, Thomas S. A. HeugebaertContinuous flow operation greatly improved the oxidation of biorenewable furfural to maleic anhydride, achieving improved productivity while adhering to green chemistry principles.
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