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Perovskite-triggered dual exsolution of oxygen-deficient CeO2 matrix and NiFe nanoalloys for enhanced CO2 electrolysis
DOI: 10.1039/D5GC04390E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Biao Ouyang, Ming Yang, Lin-Bo Liu, Shuo Liu, Yan Li, Xian-Zhu Fu, Yifei Sun, Subiao Liu, Jing-Li LuoSr1.95Ce0.05Fe1.3Ni0.2Mo0.5O6−δ with optimal Ce doping allowed in situ co-exsolving CeO2 phase and NiFe nanoalloys on the surface, which achieved a high current density of 1.57 A cm−2 at 1.5 V and 850 °C with a CO faradaic efficiency of over 96%.
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Oxygen vacancy-hydroxyl frustrated Lewis pairs enabling CO2 cycloaddition for halogen-free synthesis of cyclic carbonates
DOI: 10.1039/D5GC04831A, PaperChengguang Yue, Jiaxin Li, Mei-Yan Wang, Zhiyi Yang, Tiantian Xiao, Ji Qi, Shouying Huang, Yue Wang, Liang-Nian He, Xinbin Ma
A series of Co3O4 catalysts with unique oxygen vacancy-hydroxyl FLPs were developed. The FLPs breaks the trade-off between CO2 adsorption and dissociation via forming a metastable d-HCO3 species, enabling the efficient synthesis of cyclic carbonates.
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From lab-scale performance to field barriers: electrocatalytic nitrate treatment for sustainable water remediation
DOI: 10.1039/D5GC04166J, Tutorial ReviewZhenlin Mo, Wei Guo, Laiji Xu, Yiwen Chen, Shaoqi Zhou, Baojun Liu
A green circular economy system for converting industrial wastewater (nitrates) into agricultural resources (ammonia, energy).
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Directional CO spillover promotes C–N coupling for highly selective electrocatalytic urea production
DOI: 10.1039/D5GC03681J, PaperSheng Chang, Jing Gao, Yimin Xuan, Kui Wang
The tandem Zn@Cu electrode enables spontaneous CO spillover from Zn to Cu, which boosts the *CO coverage on Cu and facilitates efficient C–N coupling to synthesize urea.
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An unexpected transition-metal free regioselective cyclization of alkynyl-tethered indoles to prepare indole-fused azepino[2,1-b]quinazolinones and spiroindole-pyrrolo[2,1-b]quinazolinones
DOI: 10.1039/D5GC04267D, PaperPei-Sen Zou, Yi-Fan Geng, Xiao-Qing Liu, Jun-Cheng Su, Cheng-Xue Pan, Dong-Liang Mo, Gui-Fa Su
A base-promoted atom economical and unexpectedly selective cyclization strategy was developed for the synthesis of indole-fused azepino[2,1-b]quinazolinones and spiroindole-pyrrolo[2,1-b]quinazolinones.
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An innovative microreactor approach for sustainable biodiesel production: process design, continuous purification and comparative LCA
DOI: 10.1039/D4GC06538G, PaperCheng-You Yang, Cheng-Yu Wang, Ni Ni Myint, Yi-Chun Chen, Penjit Srinophakun, Ya-Yu Chiang
A continuous flow microreactor system with a helix wire-based biphasic separator achieves high-purity FAME with reduced waste and energy consumption, as confirmed by LCA, marking a significant advancement in sustainable biofuel processing.
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Correction: Evaluating the possibilities and limitations of the pyrometallurgical recycling of waste Li-ion batteries using simulation and life cycle assessment
Green Chem., 2025, 27,13513-13513
DOI: 10.1039/D5GC90193F, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Marja Rinne, Heikki Lappalainen, Mari Lundström
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DOI: 10.1039/D5GC90193F, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Marja Rinne, Heikki Lappalainen, Mari LundströmThe content of this RSS Feed (c) The Royal Society of Chemistry
Constructing a Bi–O–Mo electronic bridge bond and active sites over Bi/Bi2MoO6/Bi24O31Br10 to boost the stepwise transfer of electrons for efficient CO2 photoreduction
DOI: 10.1039/D5GC02374B, PaperHuihui Ding, Huanhuan Wu, Jun Ma, Xiang Li, Shuangshuang Huai, Shijian Zhang, Wenbin Ruan, Xiuxiu Huang, Xiufang Wang, Wenjie Xie
A Bi–O–Mo bridge bond was introduced between BMO and BOB interfaces and surface metal active sites were modified. The catalyst accelerates multi-electron photocatalytic reduction processes and reduces the reaction energy barrier for CO2 reduction.
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Sustainable high-efficiency photocatalytic lithium recovery from spent LiFePO4 batteries: green process design and performance validation
DOI: 10.1039/D5GC01122A, PaperYinzhuang Fang, Yurong Han, Menglong Yan, Changwen Li, Xiaolong Yan, Jinwei Li, Haowen Wei, Xianbao Wang, Tao Mei
Recycling spent lithium iron phosphate batteries is of great significance for both economic and environmental protection.
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Uniformly crosslinked algal bioplastic with triggerable decomposition in salt water
DOI: 10.1039/D5GC02866C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Andrew E. Ashmar, Eric J. Beckman, Susan K. Fullerton-ShireyDeveloping more degradable plastics is key to reducing marine pollution and microplastic-related ecological harm.
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Artificial intelligence-driven dynamic regulation for high-efficiency gentamicin C1a production
DOI: 10.1039/D5GC02507A, PaperFeng Xu, Yuan Wang, Hao Gao, Kaihao Hu, Rong Ben, Ali Mohsin, Yuanxin Guo, Xu Li, Hui Wu, Haifeng Hang, Ju Chu, Xiwei Tian
The industrial biosynthesis of complex antibiotics such as gentamicin C1a requires precise, dynamic control of microbial metabolism.
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Green and sustainable itaconic acid-based vitrimers with rapid stress relaxation, superior fire safety, and recyclability via synergistic roles of multiple dynamic bonds
DOI: 10.1039/D5GC04554A, PaperYuzhao Qi, Yinliang Zhang, Shiyu Ou, Guangwu Zhuo, Hongju Zeng, Yufei Lao, Junfeng Wang, Qingwen Wang, Chuigen Guo
Complementary functions and synergy between multiple dynamic covalent bonds to construct the itaconic acid-based epoxy vitrimers with functional customisation.
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Chalcogenide electrocatalysts for electrolytic seawater oxidation: design strategies for enhanced activity and selectivity
DOI: 10.1039/D5GC03454J, Tutorial ReviewQing Li, Chenxi Liu, Zefeng Teng, Rui Zhang, Xu Liu, Jia Liu, Zhenyu Xiao, Jingqi Chi, Jianping Lai, Lei Wang
This review systematically summarizes recent advances in chalcogenide-based catalysts for OER in seawater, focusing on strategies for enhancing their activity and chloride inhibition capabilities.
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Metal-free electrohalogenation of olefins with aqueous NaX mediators
DOI: 10.1039/D5GC04102C, CommunicationZhe Zhang, Quanjin Rong, Shengkang Qian, Jianyou Zhao, Chengling Deng, Jiaoyang Liu, Fan Wang, Shuai Liu, Zhong-Quan Liu
We have developed a practical and diverse chlorination of alkenes via metal-free electrochemistry. By simply tuning the substitution pattern of the alkene, selective access to vicinal dichlorides, monochlorides, or allylic chlorides can be achieved.
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Expanding and recycling a water-resistant bioderived rigid foam using CO2-responsive amines and carbonated water
DOI: 10.1039/D4GC06165A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Daniel Barker, Michael F. Cunningham, Guojun Liu, Philip G. JessopBy combining renewable resources with CO2-responsive functionalities, a sustainable foam packaging material was developed. This bioderived foam can be recycled by dissolving it into carbonated water and expanding it into a new foam product.
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From lignin to market: a technical and economic perspective of reductive depolymerization approaches
DOI: 10.1039/D5GC02316E, Critical Review
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Brent Daelemans, Balaji Sridharan, Paul Jusner, Agneev Mukherjee, Jiazhao Chen, Jacob K. Kenny, Miet Van Dael, Karolien Vanbroekhoven, Peter J. Deuss, Michael L. Stone, Elias FeghaliThe industrial potential of pilot-scale reductive depolymerization approaches is critically assessed from a technical, techno-economic, and application point of view.
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All-climate all-solid-state batteries enabled by high-entropy amorphous oxyhalide solid electrolytes
DOI: 10.1039/D5GC03551A, PaperShufeng Song, Wei Xue, Yumei Wang, Zhongting Wang, Yanming Cui, Zhixu Long, Hongyang Shan, Ning Hu, Jingfeng Wang, Fusheng Pan
A high-entropy mixed-ion strategy overcomes ASSBs’ temperature limits. The engineered high-entropy amorphous oxyhalide achieves high ionic conductivity (7.1 mS cm−1) and enhanced electrochemical stability, enabling all-climate ASSBs.
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Synergistic recycling of polycarbonate: efficient BPA recovery integrated with CO2 utilization to produce valuable chemicals
DOI: 10.1039/D5GC02387D, PaperYue Bai, Minghao Zhang, Siming Zhu, Zhuo Wang, Yu Liu, Jianxiu Hao, Huacong Zhou, Qingqing Mei
This work introduces a synergistic strategy that simultaneously converts PC and its hydrolysis by-product CO2 into high-value products (BPA and PDO), achieving full carbon utilization with no CO2 emissions.
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Photocatalytic transformation of aliphatic heterocycles and electron-poor alkenes into functionalized heteroarenes
DOI: 10.1039/D5GC04418A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Lorenzo Di Terlizzi, Davide Ravelli, Burkhard KönigThe merger of decatungstate photocatalysis and cobaloxime catalysis enabled the preparation of functionalized heteroarenes via a hydroalkylation/aromatization sequence starting from largely available aliphatic heterocycles and electron-poor olefins.
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Scalable glycolysis-based depolymerization of polyurethane foam waste enabled by ionic liquids
DOI: 10.1039/D5GC03643G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Francisco Velasco, Rocio Villa, Nicolas Alonso, Rebeca Salas, Jairton Dupont, Eduardo Garcia-Verdugo, Pedro LozanoA sustainable and scalable strategy for the glycolytic depolymerization of polyurethane foam (PUF) waste, based on the ionic liquid technology under mild conditions, provides a suitable starting material for re-synthesis of new flexible PUF.
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