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Sulphur-doped graphene quantum dot electrolyte additives for enhanced cycling stability of aqueous zinc-ion batteries
DOI: 10.1039/D5GC02211H, PaperJuanyun Li, Bin Wang, Zaohong Zhang, Peng Xie, Yanming Huang, Chengjie Xin, Ding Chen
Sulfur-doped graphene quantum dots with abundant functional groups were synthesized and their incorporation as electrolyte additives disrupts conventional solvated structures, enabling excellent electrochemical performance in assembled batteries.
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Upcycling spent polycrystal LiNi1/3Co1/3Mn1/3O2 cathodes into single-crystal Ni-rich materials via the “four-in-one” upcycling regeneration strategy
DOI: 10.1039/D5GC03333K, PaperFu Wan, Da Yang, Ruiqi Liu, Yupeng Lin, Wenwei Yin, Kaida Hu, Changding Wang, Yujie Zheng, Weigen Chen
The “four-in-one” upgraded regeneration strategy achieved the directional regeneration of waste low-nickel polycrystalline NCM111 to the molybdenum-gradient-doped nickel-rich single crystal NCM811.
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A liquid molten salt catalyst with dynamic active sites for efficient conversion of CO2 to CO
DOI: 10.1039/D5GC03584H, PaperRui Yu, Baoxin Gao, Xi Xiong, Kaifa Du, Kaiming Wu
A novel liquid molten salt catalyst for converting CO2 to CO via the reverse water–gas shift (RWGS) reaction.
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Upgrading biomass-derived platform chemicals into biofuel additives in synergism with H2O2 via a ZnIn2S4 photocatalyst: towards solar fuels
DOI: 10.1039/D5GC02763B, PaperArpna Jaryal, Shivali Dhingra, Nisha Mehla, Md. Ehesan Ali, Kamalakannan Kailasam
Nothing to sacrifice: a versatile photo-redox system, i.e., ZnIn2S4, for synergistically producing bio-fuel additives from biomass-derived chemicals and H2O2 (a carbon-free fuel).
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Crab shell-derived chitin nanofiber separator for high-rate potassium-ion batteries
DOI: 10.1039/D5GC02731D, PaperTaohong Wang, Haoxian Shi, Junyi Wen, Donghao Yang, Boyang Zhou, Hao Xi, Zhen Zhang
Partially deacetylated chitin nanofiber separator for high-rate potassium-ion batteries
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Novel control of fractionation–depolymerization for rapid dissociation of lignin-associated xylan: toward complete lignocellulosic biomass valorization in lignin-first biorefinery
DOI: 10.1039/D5GC02925B, PaperJianyu Guan, Ho-Yin Tse, Huaimin Wang, Wancheng Zhao, Raffel Dharma Patria, Molly Meng-Jung Li, Song Cheng, Tuo Wang, Shao-Yuan Leu
Harvesting sustainable aromatic chemicals from lignocellulosic biomass is a critical part of a bio-based economy.
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Phase-change azobenzene derivatives for upgraded photon energy storage and release via molecular design
DOI: 10.1039/D5GC03447G, PaperXingtang Xu, Penghao Li, Chonghua Li, Bo Wu, Jie Feng, Wen-Ying Li
An innovative molecular design strategy is presented that can significantly enhance the energy densities of molecular solar thermal fuels by simultaneously storing photon energy and phase change energy.
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Membrane-free one-pot cascaded electrocatalytic redox of furfural into gamma-butyrolactone
DOI: 10.1039/D5GC03829D, PaperShengqin Liu, Yangxin Jin, Qi Zhu, Xiaodan Xu, Shan Shao, Kartick Chandra Majhi, Qingguo Le, Jieming Huang, Jian Zhang, Zupeng Chen, Jason Chun-Ho Lam
A green and sustainable one-pot paired electrolysis method is introduced for the conversion of furfural (FAL), a biomass-derived platform compound, into gamma-butyrolactone (GBL).
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Green and efficient cell wall nano-reconstruction under ambient temperature towards strong cellulosic aerogels
DOI: 10.1039/D5GC03785A, Paper
Open Access 
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Xiaoying Xu, Arezu Sehati, Lukas Marcos Celada, Peter Olsén, Lars Berglund, Yuanyuan LiA green and efficient approach for synthesizing strong cellulosic aerogels was developed through ambient-temperature wood cell wall nano-reconstruction, with a detailed study of the generation of mesoporosity and lumina nanofibril networks.
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Electrochemically relevant physical–chemical properties of tetraalkylammonium salts solutions in the renewable solvent dihydrolevoglucosenone (Cyrene®); electrochemical behaviour of some representative organic molecules
DOI: 10.1039/D5GC03356J, Paper
Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.José M. Ramos-Villaseñor, Jessica Sotelo-Gil, Maricarmen P. Flores-Morales, Ruben Vasquez-Medrano, Bernardo A. Frontana-UribeConductivity, viscosity, IR spectroscopy of tetraalkylammonium salts solutions in DLG, and the electrochemical behavior of representative molecules was studied.
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Revealing the roles of light and heat for enhanced interfacial charge transfer in photocatalytic conversion of methanol to formaldehyde coupled with hydrogen evolution
DOI: 10.1039/D5GC03911H, PaperHoukui Xiang, Wanqi Liu, Zhaokai Zeng, Jingxian Chen, Beile Lin, Guoliang Zhang, Xuhui Wei, Songbo Zhou, Tongqiang Xiong, Pengfei Li, Libing Qian
Photothermal catalytic methanol (CH3OH) dehydrogenation is a sustainable pathway for the co-production of hydrogen (H2) and formaldehyde (HCHO) under mild reaction conditions.
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A comprehensive review on hydrothermal humic acids: synthesis, characterization, applications, and perspectives
DOI: 10.1039/D5GC03926F, Tutorial ReviewHu Xu, Yangyang Li, Yexuan He, Xin Sheng, Zhiwei Zhao, Li Li
The synthesis and application of hydrothermal humic acids represent a carbon-negative pathway, analogous to the significance of basketball as a vital form of exercise.
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Intensifying hydrogen spillover over silicotungstic acid decorated carbon black-supported Ru by green plasma preparation for boosting the electrocatalytic hydrogen evolution reaction
DOI: 10.1039/D5GC03845F, PaperYunzhe Ma, Hong Li, Fei Gao, Yue Hua, Xiuling Zhang, Jingsen Zhang, Lanbo Di
Green plasma preparation intensified hydrogen spillover over silicotungstic acid decorated carbon black-supported Ru for boosting HER performance.
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2-Methyl-2-(pyridin-2-yl)malononitrile: a site-selective cyano transfer reagent for photocatalytic cyanation reactions
DOI: 10.1039/D5GC03425F, PaperXiang-Chuang Tan, Lei Yan, Hao-Ni Qin, Peng-Fei Xu
Herein, we report the development of a carbon-bound radical cyanating reagent, 2-methyl-2-(pyridin-2-yl)malononitrile (MPYMN), which enables metal-free photocatalytic cyanation with high reactivity and site selectivity.
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Short and sustainable synthesis of the anticancer agent tepotinib
DOI: 10.1039/D5GC04089B, CommunicationEduam O. Boeira, Angélica V. Moro, Bruce H. Lipshutz
Synthesis of the anticancer drug tepotinib was achieved in only 5 steps (3 steps in the longest linear sequence), with an overall yield of 75%.
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Eco-friendly synthesis of imine-based COFs for efficient photocatalytic H2O2 production
DOI: 10.1039/D5GC03415A, PaperYayang Wang, Ting Xu, Zhongxing Zhang, Yaowen Wang, Jiming Huang, Mi Tang, Zhengbang Wang
Imine-based COFs, synthesized via eco-friendly methods, enable efficient visible-light-driven H2O2 production with excellent photocatalytic performance.
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Ionic liquid-mediated solid–liquid extraction and separation processes for essential oils: modern trends
DOI: 10.1039/D5GC01303H, PerspectivePankaj Kumar, Sonali Khanal, Isha Soni, Pooja Shandilya, Manish Kumar, Dinesh Kumar, Tejwant Singh Kang, Vinay Chauhan
Ionic liquids (ILs) have proven to be a potential medium for the extraction and separation of essential oils (EOs) from the most varied sources.
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Skeletal editing of anthranils for chemodivergent synthesis
DOI: 10.1039/D5GC02493E, CommunicationHaixia Li, Jianming Liu, Yanping Huo, Xianwei Li, Qian Chen, Yang Gao
A skeletal editing strategy has been developed for converting readily available anthranils into divergent nitrogen-containing heterocycles with different amines.
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Chiral chlorophyll-inspired clusters steering electron transfer for enhanced CO2 photoreduction
DOI: 10.1039/D5GC03034J, PaperYin-Hua Zhu, Jian-Bo Yang, Jiu Lin Zhou, Yong-Qi Ji, Hua Mei, Yan Xu
The chiral L-Co-BPP catalyst, made from chlorophyll-like ligands, achieves an outstanding CO2 reaction rate of 65 061.6 μmol g−1 and is also active at 10% CO2.
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An activity–selectivity–stability-balanced bifunctional high-entropy phosphide for overall seawater splitting at industrial-level current density
DOI: 10.1039/D5GC03723A, PaperChangrui Feng, Yifan Zhou, Shuying Li, Yuxia Jin, Meng Chen, Rui Yang, Wenjia Zhou, Zhengkun Xie, Xiumin Li, Xiangyu Chen, Wenhao Lian, Abuliti Abudula, Guoqing Guan
A high-entropy (NiCoFeMnCu)2P/C catalytic system was constructed to reconcile critical activity–selectivity–stability trade-offs in seawater electrolysis.
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