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Design an artificially concise biocatalytic cascade for the manufacture of Rebaudioside M from a naturally derived steviol glycosides mixture
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC03693C, PaperZhengshan Luo, Xupeng Guo, Zhiwei Deng, Dong Guo, Yan Zhang, Changmei Liu, Zhenbo Yuan, Yijian Rao
Rebaudioside M (Reb M) is an important natural sweetener due to its high sweetness, low calorie content, and pleasant taste, but its low natural abundance and costly, unsustainable extraction limit...
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DOI: 10.1039/D5GC03693C, PaperZhengshan Luo, Xupeng Guo, Zhiwei Deng, Dong Guo, Yan Zhang, Changmei Liu, Zhenbo Yuan, Yijian Rao
Rebaudioside M (Reb M) is an important natural sweetener due to its high sweetness, low calorie content, and pleasant taste, but its low natural abundance and costly, unsustainable extraction limit...
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Hydrogen-driven, ATP-dependent biocatalytic reduction of carboxylic acids under non-explosive conditions
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC03751D, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Marianna Karava, Qian Liang, Elske van der Pol, Margit Winkler, Robert Kourist
The reduction of carboxylic acids to alcohols is a key chemical transformation. We present a whole-cell biocatalyst employing carboxylic acid reductases and H2 for cofactor regeneration. H2 as a reductant...
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DOI: 10.1039/D5GC03751D, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Marianna Karava, Qian Liang, Elske van der Pol, Margit Winkler, Robert KouristThe reduction of carboxylic acids to alcohols is a key chemical transformation. We present a whole-cell biocatalyst employing carboxylic acid reductases and H2 for cofactor regeneration. H2 as a reductant...
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Adsorption-supported ozonation of complex mariculture wastewater pharmaceuticals by greener (Ni/Fe-C) nano-composite derived by co-pyrolysis of Coconut Shell & partially reduced iron: mechanism, and implications
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC05065K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Muhammad Noman, Guangwei Yu
Undeniably, intensive utilization of emerging antibiotics like Oxytetracycline (OTC) and other complex pharmaceuticals in mariculture poses an ecological threat. Similarly, hazardous wastes like partially reduced iron ore (RI) and coconut...
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DOI: 10.1039/D5GC05065K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Muhammad Noman, Guangwei YuUndeniably, intensive utilization of emerging antibiotics like Oxytetracycline (OTC) and other complex pharmaceuticals in mariculture poses an ecological threat. Similarly, hazardous wastes like partially reduced iron ore (RI) and coconut...
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Photo-coupled electrocatalytic conversion of CO2-to-CO over cobalt phthalocyanine modified POM-K8Ta6O19 Z-scheme photocathodes
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04093K, PaperChen Liu, Linjie Song, Wanwan Wu, Haiyan Li, Dong-Bin Dang, Yan Bai
The construction of inorganic-organic heterojunctions, inspired by natural photosynthesis, is regarded as an effective strategy for designing highly efficient photoelectrocatalysts used for the CO2 conversion. In this study, we successfully...
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DOI: 10.1039/D5GC04093K, PaperChen Liu, Linjie Song, Wanwan Wu, Haiyan Li, Dong-Bin Dang, Yan Bai
The construction of inorganic-organic heterojunctions, inspired by natural photosynthesis, is regarded as an effective strategy for designing highly efficient photoelectrocatalysts used for the CO2 conversion. In this study, we successfully...
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Integrating catalytic fractionation and microbial funneling to produce 2-pyrone-4,6-dicarboxylic acid and ethanol
DOI: 10.1039/D5GC03986J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Canan Sener, Emmanuel A. Aboagye, Steven D. Karlen, Jose M. Perez, German E. Umana, Yaoping Zhang, José Serate, Timothy J. Donohue, Daniel R. Noguera, Christos T. MaraveliasConcerted biomass fractionation and lignin depolymerization process integrated with microbial funneling to PDC, ethanol, and electricity results in a 29% reduction in the minimum selling costs for PDC and reduced environmental impact.
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Electroenzymatic Cascade Synthesis of Chiral α-Substituted Aromatic Halohydrins from Alkene: A Green and Stereoselective Approach
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04446D, PaperYihang Dai, chenyi Zhang, Xinjia Yu, Chuang Du, Fengxi Li, Lei Wang
Chiral α-substituted aromatic halohydrins are vital intermediates in pharmaceutical development and asymmetric synthesis. Herein, we report a sustainable electroenzymatic cascade for their synthesis directly from alkene. This one-pot strategy integrates...
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DOI: 10.1039/D5GC04446D, PaperYihang Dai, chenyi Zhang, Xinjia Yu, Chuang Du, Fengxi Li, Lei Wang
Chiral α-substituted aromatic halohydrins are vital intermediates in pharmaceutical development and asymmetric synthesis. Herein, we report a sustainable electroenzymatic cascade for their synthesis directly from alkene. This one-pot strategy integrates...
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Metal-Free Stereoselective C(sp3)-H Indolation of N-heterocycles to Potent Antimicrobial Non-Canonical Tryp-Pro Hybrids
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04622J, PaperSubhajit Saha, Soumya Ranjan Bag, Abdul Akhir, Deepanshi Saxena, Rahul Maitra, Sidharth Chopra, Chandan K. Jana
Indolyl aliphatic N-heterocycles are widely present as the key structural unit of many natural products and unnatural bioactive molecules. The known synthetic methods of indolyl N-heterocycles rely on metallic reagents/catalysts,...
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DOI: 10.1039/D5GC04622J, PaperSubhajit Saha, Soumya Ranjan Bag, Abdul Akhir, Deepanshi Saxena, Rahul Maitra, Sidharth Chopra, Chandan K. Jana
Indolyl aliphatic N-heterocycles are widely present as the key structural unit of many natural products and unnatural bioactive molecules. The known synthetic methods of indolyl N-heterocycles rely on metallic reagents/catalysts,...
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Linear Paired Electrolysis Enabled Dearomative [3 + 2] Cycloadditions of Indoles and Benzofurans with Vinyl Azides †
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04148A, PaperShaoxiong Yang, Yanren Zhu, Enfan Pu, Piaopiao Jiang, Xiong Li, Hongbin Zhang, Jingbo Chen
Linear paired electrolysis is an ideal yet relatively rare electrochemical approach that offers significant advantages for constructing fused heterocyclic frameworks. Herein, we report an efficient protocol for dearomative [3 +...
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DOI: 10.1039/D5GC04148A, PaperShaoxiong Yang, Yanren Zhu, Enfan Pu, Piaopiao Jiang, Xiong Li, Hongbin Zhang, Jingbo Chen
Linear paired electrolysis is an ideal yet relatively rare electrochemical approach that offers significant advantages for constructing fused heterocyclic frameworks. Herein, we report an efficient protocol for dearomative [3 +...
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Overcoming thermodynamic incompatibilities with photons: multi-carbon hydrocarbons from methane and carbon dioxide via a hybrid photocatalytic dry reforming/Fischer-Tropsch process
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04326C, CommunicationHiroaki Kaneko, Shusaku Shoji, Yohei Cho, Tomotaka Sugimura, Ayako Hashimoto, Hideki Abe, Akira Yamaguchi, Masahiro Miyauchi
Combining methane dry reforming (DRM) and Fischer-Tropsch synthesis (FTS) enables the conversion of greenhouse gases into valuable hydrocarbons via syngas. However, DRM and FTS have contradictory thermodynamic conditions. This study...
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DOI: 10.1039/D5GC04326C, CommunicationHiroaki Kaneko, Shusaku Shoji, Yohei Cho, Tomotaka Sugimura, Ayako Hashimoto, Hideki Abe, Akira Yamaguchi, Masahiro Miyauchi
Combining methane dry reforming (DRM) and Fischer-Tropsch synthesis (FTS) enables the conversion of greenhouse gases into valuable hydrocarbons via syngas. However, DRM and FTS have contradictory thermodynamic conditions. This study...
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Recycling of Spent Lithium-ion Batteries via Hydrothermal Process
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04598C, Critical ReviewYafei Shen
Hydrothermal treatment has demonstrated great potential in regeneration and terminal recycling spent LIB cathode materials. On the one hand, hydrothermal regeneration is a hydrothermal reaction that uses a lithium-containing solution...
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DOI: 10.1039/D5GC04598C, Critical ReviewYafei Shen
Hydrothermal treatment has demonstrated great potential in regeneration and terminal recycling spent LIB cathode materials. On the one hand, hydrothermal regeneration is a hydrothermal reaction that uses a lithium-containing solution...
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Correction: Biocatalytic conversion of lignin model oligomer using a laccase-mediator system
Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC90198G, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Christopher W. J. Murnaghan, William G. Forsythe, Jack H. Lafferty, Alison Woodward, Gary N. Sheldrake
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DOI: 10.1039/D5GC90198G, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Christopher W. J. Murnaghan, William G. Forsythe, Jack H. Lafferty, Alison Woodward, Gary N. SheldrakeTo cite this article before page numbers are assigned, use the DOI form of citation above.
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Electron-Withdrawing Group in Covalent Organic Frameworks Induced Separated Redox Centers Toward Enhanced Overall H2O2 Photosynthesis in Pure Water
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04352B, PaperLijun Liao, Wenjiao Wang, Wei Qin, Hongqi Chu, Xuepeng Wang, Liping Guo, Zhenzi Li, Fu-Quan Bai, Wei Zhou
Conventional hydrogen peroxide (H2O2) production is energy-intensive and environmentally burdensome. Photocatalytic synthesis using covalent organic frameworks (COFs) offers a sustainable alternative. This work introduces sulfone groups into COFs via [4+2]...
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DOI: 10.1039/D5GC04352B, PaperLijun Liao, Wenjiao Wang, Wei Qin, Hongqi Chu, Xuepeng Wang, Liping Guo, Zhenzi Li, Fu-Quan Bai, Wei Zhou
Conventional hydrogen peroxide (H2O2) production is energy-intensive and environmentally burdensome. Photocatalytic synthesis using covalent organic frameworks (COFs) offers a sustainable alternative. This work introduces sulfone groups into COFs via [4+2]...
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Green Conversion of Spent Lithium-Ion Batteries via Infrared Pyrolysis: Gas-Assisted Metal Recovery and Reaction Pathway Elucidation
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC05022G, PaperMoshan Li, Zuohua Liu, Erfeng Hu, Guangwen Xu, Rui Qu, Jianglong Yu, Dean Pan, Youcai Ma
The recycling of waste lithium-ion batteries (LIBs) plays a pivotal role in the sustainable advancement of renewable energy technologies. This study presented a new technique for ex-situ recovery of cobalt...
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DOI: 10.1039/D5GC05022G, PaperMoshan Li, Zuohua Liu, Erfeng Hu, Guangwen Xu, Rui Qu, Jianglong Yu, Dean Pan, Youcai Ma
The recycling of waste lithium-ion batteries (LIBs) plays a pivotal role in the sustainable advancement of renewable energy technologies. This study presented a new technique for ex-situ recovery of cobalt...
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Electrochemical sulfonylation with sulfur dioxide: a sustainable strategy for organic synthesis
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04193G, Tutorial ReviewZhi-Long Lei, Hai-Tao Tang, Ying-Ming Pan
The utilization of organic electrochemical methods to achieve efficient and green conversion and fixation of sulfur dioxide (SO₂) has become a highly attractive research direction in the field of organic...
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DOI: 10.1039/D5GC04193G, Tutorial ReviewZhi-Long Lei, Hai-Tao Tang, Ying-Ming Pan
The utilization of organic electrochemical methods to achieve efficient and green conversion and fixation of sulfur dioxide (SO₂) has become a highly attractive research direction in the field of organic...
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In-Situ Reduction Engineering of NiFe-NiFe 2 O 4 Heterojunctions for Interfacial Coupling toward Efficient Bifunctional Zinc-Air Batteries
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04845A, PaperYi Hu, Ning Han, Yiting Wu, Cong Han, Lizi He
Single-component catalysts face inherent challenges in striking a balance between the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER) due to their sluggish kinetics and divergent reaction requirements....
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DOI: 10.1039/D5GC04845A, PaperYi Hu, Ning Han, Yiting Wu, Cong Han, Lizi He
Single-component catalysts face inherent challenges in striking a balance between the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER) due to their sluggish kinetics and divergent reaction requirements....
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Redox-mediated electrified synthesis of benzaldehyde
DOI: 10.1039/D5GC04073F, PaperJingkai Yan, Manohar Salla, Yuxi Song, Hang Zhang, Linbo Wang, Dao Gen Lek, Mengxiao Li, Junzhe Pei, Qinghua Xu, Qing Wang
A vanadium redox flow cell enables the electrified oxidation of benzyl alcohol to benzaldehyde with nearly 100% selectivity, preventing overoxidation and concurrently producing hydrogen, offering a scalable and energy-efficient synthesis strategy.
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Electrolyte additive enabling dual kinetic regulation for stable zinc anodes in aqueous zinc batteries
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04716A, PaperHuidi Shi, Yiqun Du, Liu Yang, Bingying Sun, Ximing Yu, Anbin Hu, Shuhua Yang, Jinkai Li, Bingqiang Cao
The practical deployment of aqueous zinc batteries (AZBs) is impeded by hydrogen evolution reactions (HER) and uncontrolled dendrite formation on the zinc anode. This study proposes a green electrolyte engineering...
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DOI: 10.1039/D5GC04716A, PaperHuidi Shi, Yiqun Du, Liu Yang, Bingying Sun, Ximing Yu, Anbin Hu, Shuhua Yang, Jinkai Li, Bingqiang Cao
The practical deployment of aqueous zinc batteries (AZBs) is impeded by hydrogen evolution reactions (HER) and uncontrolled dendrite formation on the zinc anode. This study proposes a green electrolyte engineering...
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Unmodified technical lignins as sustainable binders in structural biocomposites
DOI: 10.1039/D5GC04157K, PaperLuisa Scolari, Oliver Musl, Nadine Kohlhuber, Irina Sulaeva, Stefan Grasböck, Josef Füssl, Michael Harasek, Antje Potthast, Markus Lukacevic
Fully biobased lignocellulosic biocomposites were fabricated by impregnating holocellulose fiber sheets with the ethanol-soluble fraction of technical lignins, followed by hot-pressing.
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Trace-LiCl-assisted Synthesis of High-Loading Ordered Pt3Co Intermetallic Catalysts for Oxygen Reduction Reaction in Fuel Cells
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC05077D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yutao Ni, Jiahui Song, Huiying Lan, Xue Jing, Wenwen Shi, Ruimin Ding, Xi Yin
The synthesis of high-loading platinum intermetallic compounds (IMCs) for proton exchange membrane fuel cells (PEMFCs) remains challenging due to severe nanoparticle agglomeration and inhomogeneity during high-temperature annealing.Here, we report a...
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DOI: 10.1039/D5GC05077D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yutao Ni, Jiahui Song, Huiying Lan, Xue Jing, Wenwen Shi, Ruimin Ding, Xi YinThe synthesis of high-loading platinum intermetallic compounds (IMCs) for proton exchange membrane fuel cells (PEMFCs) remains challenging due to severe nanoparticle agglomeration and inhomogeneity during high-temperature annealing.Here, we report a...
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Following forest cues for the harvest optimization of tomorrow's biofeedstocks
DOI: 10.1039/D5GC04279H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Robyn C. O'Halloran, Alison J. Shapiro, Yagya Gupta, Anna Long, Sara G. Haney, Yuichiro Otsuka, Sunitha Sadula, Dionisios G. Vlachos, Delphis F. Levia, Thomas H. EppsHarvest optimization offers an effective strategy for maximizing lignin valorization yields and overall biorefinery production of fuels, chemicals, and materials.
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