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Using a bioderived CO2-responsive polymer as an easily removed pressure sensitive adhesive

Chemical News - 28 July, 2025 - 15:12

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC00630A, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Daniel Barker, Shannon Whitty, Tobias Robert, Parisa Bayat, Marc A. Dubé, Michael F. Cunningham, Guojun Liu, Philip G. Jessop
Combining renewable resources with CO2-responsive functionalities produced a pressure sensitive adhesive with adhesive properties like commercial cellophane tapes but can be easily removed from substrates using carbonated water at the end of life.
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From aspiration to action: evolving the mission of Green Chemistry

Chemical News - 28 July, 2025 - 15:12

Green Chem., 2025, 27,8357-8359
DOI: 10.1039/D5GC90116B, EditorialJavier Pérez-Ramírez, Michael A. Rowan
Outlining how the journal is evolving to support a growing, global community and how Green Chemistry will continue to move from aspiration to action.
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Nickel catalyzed hydrodechlorination and CO functionalization of polyvinyl chloride

Chemical News - 28 July, 2025 - 15:12

Green Chem., 2025, 27,8559-8568
DOI: 10.1039/D5GC01890K, PaperAyon Das, Megan E. Fieser
Earth-abundant Ni-catalyzed poly(vinyl chloride) hydrodechlorination leads to a polyethylene like product with in-chain incorporation of carbonyl groups using sodium formate as a source of both H and CO, yielding NaCl as a benign co-product.
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Single step, one-pot, catalyst-free upcycling of polyethylene terephthalate into biphasic carbon dots and high-purity terephthalic acid

Chemical News - 28 July, 2025 - 15:12

Green Chem., 2025, 27,8660-8673
DOI: 10.1039/D5GC01431J, PaperKevin Brian, Mahmoud Elbeh, Mohammed Abdelhameed, Batoul Khlaifat, Fatma Alrebh, Liaqat Ali, Batool Abedrabbo, Brijith Thomas, Khalil B. Ramadi
Upcycling of PET-based plastic waste into value-added nanomaterials via hydrothermal treatment. The process yields hydrophilic and hydrophobic carbon quantum dots as well as terephthalic acid.
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Green synthesis of scalable non-soluble hydrogels: rapid transesterification of maltodextrin with dimethylcarbonate using DABCO/DMSO

Chemical News - 28 July, 2025 - 15:12

Green Chem., 2025, 27,8649-8659
DOI: 10.1039/D5GC02156A, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Mohamed M. H. Desoky, Gjylije Hoti, Arshak Tsaturyan, Claudio Cecone, Fabrizo Caldera, Francesco Trotta
Green, scalable synthesis of maltodextrin hydrogels via DABCO/DMSO-catalyzed transesterification with dimethyl carbonate (∼80% yield). The hydrogels absorb 549% water, supporting sustainable materials.
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Dual enabling photomediated Knoevenagel condensation and alkene perfluoroalkylation reactions by a photoresponsive cadmium–organic framework

Chemical News - 28 July, 2025 - 15:12

Green Chem., 2025, 27,8603-8612
DOI: 10.1039/D5GC01928A, PaperNana Yuan, Jia Cao, Yixia Ren, Xiufang Hou, Sanping Chen
A porous Cd-MOF can not only effectively photocatalyze the Knoevenagel condensation reaction as the first MOF-based catalyst, but also catalyze the atom transfer radical addition reaction of olefins and perfluoroalkyl iodides under blue LED light.
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A phase-transfer-assisted strategy for oxidation-based biomass valorization

Chemical News - 28 July, 2025 - 15:12

Green Chem., 2025, 27,8594-8602
DOI: 10.1039/D5GC01816A, PaperJunhao Wang, Baoyin An, Pengfei Li, Huili Zhang, Yunming Fang
As the world's only carbon-containing renewable resource, lignocellulose utilization oriented toward high-value compounds under mild conditions is key to the sustainability of biorefineries.
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A catechol-catalyzed photocatalytic carbonylative four-component reaction of alkylboronic acids with aldehydes and amines

Chemical News - 28 July, 2025 - 15:12

Green Chem., 2025, 27,8492-8497
DOI: 10.1039/D5GC02383A, CommunicationOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Qiangwei Li, Le-Cheng Wang, Xiao-Feng Wu
A catechol-catalyzed photo-induced four-component carbonylation reaction of alkylboronic acids with aldehydes and amines for the direct synthesis of α-aminoketones has been developed.
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Aqueous liquid–liquid phase separation (AqLLPS) droplet microreactors for biocatalysis

Chemical News - 28 July, 2025 - 15:12

Green Chem., 2025, 27,8448-8466
DOI: 10.1039/D5GC02073E, Tutorial ReviewFutai Du, Huan Xin, Huiyuan Zheng, Weijiang Wang, Hao Yuan, Chaolong Liu, Tao Meng, Qingming Ma
This review summarizes aqueous liquid–liquid phase separation (AqLLPS) mechanisms, design strategies, and applications for biocatalysis, including enzymatic synthesis, biosensing, and therapeutics.
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MOF-derived CoSx as a bifunctional electrocatalyst for efficient sulfide oxidation and coupled ammonia synthesis

Chemical News - 28 July, 2025 - 15:12

Green Chem., 2025, 27,8637-8648
DOI: 10.1039/D5GC01690H, PaperKwangyeol Baek, Tianlei Li, Changsoo Lee, Wenzhen Li, Kwiyong Kim
A MOF-derived CoSx catalyst enables efficient sulfide oxidation and nitrate reduction, offering an energy-saving strategy for ammonia synthesis and pollutant remediation via bifunctional electrolysis.
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Covalent organic framework-derived highly dispersed Pt single atoms collaborate with Pt nanoclusters electrocatalyst for acid hydrogen evolution

Chemical News - 28 July, 2025 - 15:12

Green Chem., 2025, 27,8569-8575
DOI: 10.1039/D4GC05667A, PaperHuihui Zhao, Xinghao Zhang, Chengcheng Yu, Wenya Gao, Xiuxiu Chen, Haikuo Lan, Xiaorong Xin, Kang Liu, Dingxuan Ma
A promising HER electrocatalyst characterized by dispersed Pt single atoms and ultrafine Pt nanoclusters was synthesized using hard template method combined with ion adsorption and substitution.
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Bio-derived dimethyl itaconate: a sustainable, low-cost electrolyte additive for high-performance lithium batteries

Chemical News - 28 July, 2025 - 15:12

Green Chem., 2025, 27,8613-8624
DOI: 10.1039/D5GC01367D, PaperChengliang Wang, Mingming Zhou, Lintong Zhou, Le Chang, Jianjiang He, Wei Zhao, Jingjiang Sun, Qingfu Wang
Bio-based dimethyl itaconate stabilizes anode and cathode interfaces via forming robust SEI/CEI; providing a sustainable, cost-effective, and industrially scalable electrolyte additive alternative to vinylene carbonate for advanced Li-ion batteries.
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Alternating current enabled para-selective C(sp2)–H/N–H cross-coupling of aniline

Chemical News - 28 July, 2025 - 15:12

Green Chem., 2025, 27,8498-8504
DOI: 10.1039/D5GC01992C, CommunicationZhaoliang Yang, Haiyan Du, Yuan Zhou, Mingming Yu, Jianye Zhang
This study reports an AC electrochemical technique using polarity reversal to enable metal/oxidant-free, para-selective amination of arylamines, accommodating diverse aniline substrates with excellent regioselectivity.
The content of this RSS Feed (c) The Royal Society of Chemistry

Base-catalyzed cascades of monosaccharide conversion to formic acid: isotope tracking reveals pathways and their optimal usage under mild conditions in water

Chemical News - 28 July, 2025 - 15:12

Green Chem., 2025, 27,8625-8636
DOI: 10.1039/D5GC01907A, PaperStefan S. Warthegau, Mette-Maya Siewertsen, Robert Madsen, Sebastian Meier
We use real-time isotope tracking to resolve the complex pathways of glucose conversion to formate and its byproducts, which are shown to operate under kinetic control in water. Factors determining process efficiency are clarified.
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Electrochemical Ni–H catalysis for selective tail-to-tail reductive dimerization of terminal alkynes to access 2,3-dibranched butadienes

Chemical News - 28 July, 2025 - 15:12

Green Chem., 2025, 27,8549-8558
DOI: 10.1039/D5GC02238J, PaperShide Lv, Mingming Yu, Yinglong Ni, Tiantian Huang, Hong Yi, Aiwen Lei
Reductive dimerization of terminal alkynes offers a direct route to synthesize diverse 2,3-branched-1,3-diene frameworks.
The content of this RSS Feed (c) The Royal Society of Chemistry

Photocatalytic 1,2-thiosulfonylation of alkenes with thiophenols and sulfonyl chlorides promoted by directly knitted copper polymers

Chemical News - 28 July, 2025 - 15:12

Green Chem., 2025, 27,8585-8593
DOI: 10.1039/D5GC02121A, PaperLijie Chen, Kai Zhang, Yajing Shen, Zhen Chen, Weiwei Fang
A three-component photocatalytic 1,2-thiosulfonylation reaction of alkenes with thiophenols and sulfonyl chloride was promoted by using a rationally designed copper-containing hypercrosslinked polymer via the “direct knitting” strategy.
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Overcoming the conversion reaction limitation with a dual-phase sulfide-based cathode for all-solid-state lithium–sulfur batteries

Chemical News - 28 July, 2025 - 15:12

Green Chem., 2025, 27,8576-8584
DOI: 10.1039/D5GC01720C, PaperRuojian Ma, Yingzuo He, Minghao Ruan, Ruyi Fang, Xinxu Wang, Jun Zhang, Yongping Gan, Xinping He, Hui Huang, Xinhui Xia, Wenkui Zhang, Xinyong Tao, Min Fan, Yang Xia
A dual-phase sulfide-based cathode integrating CoS2 as an active site enhances cathode utilization and cycling stability of all-solid-state lithium–sulfur batteries.
The content of this RSS Feed (c) The Royal Society of Chemistry

Intensification of wheat straw autohydrolysis at minimal water input: Advancing a novel hemicellulose-first approach

Chemical News - 28 July, 2025 - 15:12

Green Chem., 2025, 27,8532-8548
DOI: 10.1039/D5GC02300A, PaperStanislav Parsin, Martin Kaltschmitt
The autohydrolysis of wheat straw, as a key step in a hemicellulose-first concept, was investigated with a focus on separating xylose-based oligomers and water-soluble polymers.
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The reaction of maleic anhydride with alkenes: a review on the mechanisms involved in the reaction of maleic anhydride with lipids

Chemical News - 28 July, 2025 - 07:05

Green Chem., 2025, 27,8386-8413
DOI: 10.1039/D5GC00543D, Critical ReviewShamseldin A. Mohamed, Mildrède Debello, Justine Cantot, Stéphane Lavaud, Guillaume Chollet, Clémence Queffélec, Emmanuel Chailleux
Maleic anhydride is one of the most widely used anhydrides after acetic and phthalic anhydride and its market has grown rapidly over the last century.
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Natural deep eutectic solvents (NaDES): green solvents for pharmaceutical applications and beyond

Chemical News - 25 July, 2025 - 11:42

Green Chem., 2025, 27,8360-8385
DOI: 10.1039/D4GC06386D, Critical ReviewOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Emma Chevé-Kools, Young Hae Choi, Catherine Roullier, Gwenaël Ruprich-Robert, Raphaël Grougnet, Florence Chapeland-Leclerc, Frank Hollmann
This review first provides a comprehensive overview of NaDES theory and subsequently explores all potential applications of NaDES in the pharmaceutical industry, highlighting overlooked issues such as toxicity and process limitations.
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